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A cyclobutanone-based tandem free radical rearrangement

  • University of Pittsburgh

Research output: Contribution to journal › Article › peer-review

Abstract

Free radical reaction of endo-haloalkylbicyclo[4.2.0]oct-2-en-7-ones 1 and 11 leads to sequential rearrangement and formation of the novel, bridged tricyclic ketones 2 and 13. A mechanism for this unusual transformation is proposed.

Original languageEnglish
Pages (from-to)5563-5566
Number of pages4
JournalTetrahedron Letters
Volume35
Issue number31
DOIs
StatePublished - Aug 1 1994

ASJC Scopus Subject Areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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