Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]

Suzanne McMahon; Jonathan Rochford; Yvonne Halpin; Jennifer C. Manton; Emma C. Harvey; Gregory M. Greetham; Ian P. Clark; A. Denise Rooney; Conor Long; Mary T. Pryce

doi:10.1039/c4cp03758h

Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)₅CrC(NC₄H₈)CH₃]

Suzanne McMahon
, Jonathan Rochford
, Yvonne Halpin
, Jennifer C. Manton
, Emma C. Harvey
, Gregory M. Greetham
, Ian P. Clark
, A. Denise Rooney
, Conor Long
, Mary T. Pryce

Chemistry

Dublin City University
Rutherford Appleton Laboratory
Maynooth University

Research output: Contribution to journal › Article › peer-review

Abstract

Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)₅CrC(NC₄H₈)CH₃] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.

Original language	English
Pages (from-to)	21230-21233
Number of pages	4
Journal	Physical Chemistry Chemical Physics
Volume	16
Issue number	39
DOIs	https://doi.org/10.1039/c4cp03758h
State	Published - Sep 17 2014

ASJC Scopus Subject Areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1039/c4cp03758h

Cite this

McMahon, S., Rochford, J., Halpin, Y., Manton, J. C., Harvey, E. C., Greetham, G. M., Clark, I. P., Rooney, A. D., Long, C., & Pryce, M. T. (2014). Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)₅CrC(NC₄H₈)CH₃]. Physical Chemistry Chemical Physics, 16(39), 21230-21233. https://doi.org/10.1039/c4cp03758h

@article{1ba52379bb5c4334a21aca3d22fbf738,

title = "Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]",

abstract = "Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.",

author = "Suzanne McMahon and Jonathan Rochford and Yvonne Halpin and Manton, \{Jennifer C.\} and Harvey, \{Emma C.\} and Greetham, \{Gregory M.\} and Clark, \{Ian P.\} and Rooney, \{A. Denise\} and Conor Long and Pryce, \{Mary T.\}",

year = "2014",

month = sep,

day = "17",

doi = "10.1039/c4cp03758h",

language = "English",

volume = "16",

pages = "21230--21233",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

number = "39",

}

TY - JOUR

T1 - Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]

AU - McMahon, Suzanne

AU - Rochford, Jonathan

AU - Halpin, Yvonne

AU - Manton, Jennifer C.

AU - Harvey, Emma C.

AU - Greetham, Gregory M.

AU - Clark, Ian P.

AU - Rooney, A. Denise

AU - Long, Conor

AU - Pryce, Mary T.

PY - 2014/9/17

Y1 - 2014/9/17

N2 - Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.

AB - Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.

UR - https://www.scopus.com/pages/publications/84907856139

UR - https://www.scopus.com/pages/publications/84907856139#tab=citedBy

U2 - 10.1039/c4cp03758h

DO - 10.1039/c4cp03758h

M3 - Article

C2 - 25188765

AN - SCOPUS:84907856139

SN - 1463-9076

VL - 16

SP - 21230

EP - 21233

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 39

ER -

Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)₅CrC(NC₄H₈)CH₃]

Abstract

ASJC Scopus Subject Areas

Access to Document

Other files and links

Fingerprint

Cite this