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Enhancement of optical emission and absorption by metal nanoparticles

  • Johns Hopkins University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

We provide a simple analytical model for the modification of optical properties of active molecules and other objects when they are placed in the vicinity of metal nanoparticles of sub-wavelength dimensions. Specifically, we study the enhancement of optical absorption and emission by these objects. The theory takes into account the radiative decay of the surface plasmon mode supported by the metal nanospheres - a basic phenomenon that has been ignored in electro-static treatment. In addition, the theory adequately treats the quenching effect of high order surface plasmon modes on luminescence efficiency. Using the examples of Ag and Au nanospheres embedded in GaN dielectric, we show that enhancement for each case depends strongly on the nanoparticle size and molecule-nanoparticle separation, enabling optimization for each combination of absorption cross section and original radiative efficiency. The enhancement effect is most significant for relatively weak and diluted absorbers and rather inefficient emitters that are placed at some optimal distances from the metal nanoparticles.

Original languageEnglish
Title of host publicationUltrafast Phenomena in Semiconductors and Nanostructure Materials XIV
DOIs
StatePublished - 2010
EventUltrafast Phenomena in Semiconductors and Nanostructure Materials XIV - San Francisco, CA, United States
Duration: Jan 24 2010 → Jan 27 2010

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
Volume7600
ISSN (Print)0277-786X

Conference

ConferenceUltrafast Phenomena in Semiconductors and Nanostructure Materials XIV
Country/TerritoryUnited States
CitySan Francisco, CA
Period1/24/10 → 1/27/10

ASJC Scopus Subject Areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

Keywords

  • Absorption enhancement
  • Luminescence enhancement
  • Metal nanoparticles
  • Surface plasmon

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