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Fourier transform infrared study of methanol, water, and acetic acid on MgO(100)

  • University of Massachusetts Boston

Research output: Contribution to journal › Article › peer-review

Abstract

The interactions occurring between MgO(100) surface and small molecules such as methanol, water, and acetic acid were analyzed using transmission Fourier transform infrared (FTIR) spectroscopy in conjecture with atomic force microscopy (AFM). About 15-20 crystals, cleaved along (100) faces of MgO under dry nitrogen purge, were stacked in cylindrical sample cell for spectroscopic measurements. The InSb detector was also used, coupled with CaF 2 windows, which limits frequency range of FTIR spectra collected to 4500-1800 cm -1. The results show that reactivity of MgO(100) surface to adsorbates is directly related to acidity of molecule.

Original languageEnglish
Pages (from-to)1640-1646
Number of pages7
JournalJournal of Vacuum Science and Technology A: Vacuum, Surfaces and Films
Volume22
Issue number4
DOIs
StatePublished - Jul 2004

ASJC Scopus Subject Areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

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