Intramolecular Barbier reaction of a 3-(3′-bromopropyl) bicyclo[2.2.2]oct-5-en-2-one

Wei Zhang; Paul Dowd

doi:10.1016/S0040-4039(00)60354-4

Intramolecular Barbier reaction of a 3-(3′-bromopropyl) bicyclo[2.2.2]oct-5-en-2-one

Wei Zhang
, Paul Dowd

Chemistry

University of Pittsburgh

Research output: Contribution to journal › Article › peer-review

Abstract

Intramolecular Barbier reactions, initiated with lithium or magnesium metals, were carried out on a model compound 3 and afforded four products, including the cyclic product 6 and cyclopropane-containing product 7. Single and double electron transfer sequences are proposed to explain their formation.

Original language	English
Pages (from-to)	2095-2098
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	13
DOIs	https://doi.org/10.1016/S0040-4039(00)60354-4
State	Published - Mar 26 1993

ASJC Scopus Subject Areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Intramolecular Barbier reaction of a 3-(3′-bromopropyl) bicyclo[2.2.2]oct-5-en-2-one",

abstract = "Intramolecular Barbier reactions, initiated with lithium or magnesium metals, were carried out on a model compound 3 and afforded four products, including the cyclic product 6 and cyclopropane-containing product 7. Single and double electron transfer sequences are proposed to explain their formation.",

author = "Wei Zhang and Paul Dowd",

year = "1993",

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AU - Zhang, Wei

AU - Dowd, Paul

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Y1 - 1993/3/26

N2 - Intramolecular Barbier reactions, initiated with lithium or magnesium metals, were carried out on a model compound 3 and afforded four products, including the cyclic product 6 and cyclopropane-containing product 7. Single and double electron transfer sequences are proposed to explain their formation.

AB - Intramolecular Barbier reactions, initiated with lithium or magnesium metals, were carried out on a model compound 3 and afforded four products, including the cyclic product 6 and cyclopropane-containing product 7. Single and double electron transfer sequences are proposed to explain their formation.

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U2 - 10.1016/S0040-4039(00)60354-4

DO - 10.1016/S0040-4039(00)60354-4

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JO - Tetrahedron Letters

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IS - 13

ER -

Intramolecular Barbier reaction of a 3-(3′-bromopropyl) bicyclo[2.2.2]oct-5-en-2-one

Abstract

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