Manganese(III) acetate promoted regioselective phosphonation of heteroaryl compounds

Xue Jun Mu; Jian Ping Zou; Qiu Feng Qian; Wei Zhang

doi:10.1021/ol062082n

Manganese(III) acetate promoted regioselective phosphonation of heteroaryl compounds

Xue Jun Mu
, Jian Ping Zou
, Qiu Feng Qian
, Wei Zhang

Chemistry

Soochow University
University of Pittsburgh

Research output: Contribution to journal › Article › peer-review

Abstract

A new method for direct phosphonation of thiazoles, furans, and pyrroles is introduced. Reactions of the heteroaryl compounds with dimethyl or diethyl phosphites and Mn(OAc)₃·2H₂0 under mild conditions give phosphonated products in high yield and good regioselectivity.

Original language	English
Pages (from-to)	5291-5293
Number of pages	3
Journal	Organic Letters
Volume	8
Issue number	23
DOIs	https://doi.org/10.1021/ol062082n
State	Published - Nov 9 2006

ASJC Scopus Subject Areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol062082n

Cite this

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title = "Manganese(III) acetate promoted regioselective phosphonation of heteroaryl compounds",

abstract = "A new method for direct phosphonation of thiazoles, furans, and pyrroles is introduced. Reactions of the heteroaryl compounds with dimethyl or diethyl phosphites and Mn(OAc)3·2H20 under mild conditions give phosphonated products in high yield and good regioselectivity.",

author = "Mu, \{Xue Jun\} and Zou, \{Jian Ping\} and Qian, \{Qiu Feng\} and Wei Zhang",

year = "2006",

month = nov,

day = "9",

doi = "10.1021/ol062082n",

language = "English",

volume = "8",

pages = "5291--5293",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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T1 - Manganese(III) acetate promoted regioselective phosphonation of heteroaryl compounds

AU - Mu, Xue Jun

AU - Zou, Jian Ping

AU - Qian, Qiu Feng

AU - Zhang, Wei

PY - 2006/11/9

Y1 - 2006/11/9

N2 - A new method for direct phosphonation of thiazoles, furans, and pyrroles is introduced. Reactions of the heteroaryl compounds with dimethyl or diethyl phosphites and Mn(OAc)3·2H20 under mild conditions give phosphonated products in high yield and good regioselectivity.

AB - A new method for direct phosphonation of thiazoles, furans, and pyrroles is introduced. Reactions of the heteroaryl compounds with dimethyl or diethyl phosphites and Mn(OAc)3·2H20 under mild conditions give phosphonated products in high yield and good regioselectivity.

UR - https://www.scopus.com/pages/publications/33845264775

UR - https://www.scopus.com/pages/publications/33845264775#tab=citedBy

U2 - 10.1021/ol062082n

DO - 10.1021/ol062082n

M3 - Article

C2 - 17078700

AN - SCOPUS:33845264775

SN - 1523-7060

VL - 8

SP - 5291

EP - 5293

JO - Organic Letters

JF - Organic Letters

IS - 23

ER -

Manganese(III) acetate promoted regioselective phosphonation of heteroaryl compounds

Abstract

ASJC Scopus Subject Areas

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