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Measuring disorder in irreversible decay processes

  • University of Massachusetts Boston

Research output: Contribution to journalArticlepeer-review

Abstract

Rate coefficients can fluctuate in statically and dynamically disordered kinetics. Here, we relate the rate coefficient for an irreversibly decaying population to the Fisher information. From this relationship we define kinetic versions of statistical-length squared and divergence that measure cumulative fluctuations in the rate coefficient. We show the difference between these kinetic quantities measures the amount of disorder, and is zero when the rate coefficient is temporally and spatially unique.

Original languageEnglish
Article number104107
JournalJournal of Chemical Physics
Volume141
Issue number10
DOIs
StatePublished - Sep 14 2014

ASJC Scopus Subject Areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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