One-Pot Synthesis of Polycyclic Spirooxindoles via Montmorillonite K10-Catalyzed C-H Functionalization of Cyclic Amines

Xiaofeng Zhang; Miao Liu; Weiqi Qiu; Jason Evans; Manpreet Kaur; Jerry P. Jasinski; Wei Zhang

doi:10.1021/acssuschemeng.8b00555

One-Pot Synthesis of Polycyclic Spirooxindoles via Montmorillonite K10-Catalyzed C-H Functionalization of Cyclic Amines

Xiaofeng Zhang
, Miao Liu
, Weiqi Qiu
, Jason Evans
, Manpreet Kaur
, Jerry P. Jasinski
, Wei Zhang

Chemistry

University of Massachusetts Boston
Keene State College

Research output: Contribution to journal › Article › peer-review

Abstract

A method for pot and atom economic synthesis of polycyclic spirooxindoles through α-C-H functionalization of cyclic amines has been developed. This highly efficient three-component [3+2] cycloaddition reaction was catalyzed by recyclable montmorillonite K10 and only water was produced as a byproduct.

Original language	English
Pages (from-to)	5574-5579
Number of pages	6
Journal	ACS Sustainable Chemistry and Engineering
Volume	6
Issue number	4
DOIs	https://doi.org/10.1021/acssuschemeng.8b00555
State	Published - Apr 2 2018

ASJC Scopus Subject Areas

General Chemistry
Environmental Chemistry
General Chemical Engineering
Renewable Energy, Sustainability and the Environment

Keywords

Heterogeneous catalysis
Montmorillonite K10
Recyclable
Spirooxindoles
[3+2] Cycloaddition
α-C-H functionalization

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10.1021/acssuschemeng.8b00555

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title = "One-Pot Synthesis of Polycyclic Spirooxindoles via Montmorillonite K10-Catalyzed C-H Functionalization of Cyclic Amines",

abstract = "A method for pot and atom economic synthesis of polycyclic spirooxindoles through α-C-H functionalization of cyclic amines has been developed. This highly efficient three-component [3+2] cycloaddition reaction was catalyzed by recyclable montmorillonite K10 and only water was produced as a byproduct.",

keywords = "Heterogeneous catalysis, Montmorillonite K10, Recyclable, Spirooxindoles, [3+2] Cycloaddition, α-C-H functionalization",

author = "Xiaofeng Zhang and Miao Liu and Weiqi Qiu and Jason Evans and Manpreet Kaur and Jasinski, \{Jerry P.\} and Wei Zhang",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

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doi = "10.1021/acssuschemeng.8b00555",

language = "English",

volume = "6",

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journal = "ACS Sustainable Chemistry and Engineering",

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T1 - One-Pot Synthesis of Polycyclic Spirooxindoles via Montmorillonite K10-Catalyzed C-H Functionalization of Cyclic Amines

AU - Zhang, Xiaofeng

AU - Liu, Miao

AU - Qiu, Weiqi

AU - Evans, Jason

AU - Kaur, Manpreet

AU - Jasinski, Jerry P.

AU - Zhang, Wei

PY - 2018/4/2

Y1 - 2018/4/2

N2 - A method for pot and atom economic synthesis of polycyclic spirooxindoles through α-C-H functionalization of cyclic amines has been developed. This highly efficient three-component [3+2] cycloaddition reaction was catalyzed by recyclable montmorillonite K10 and only water was produced as a byproduct.

AB - A method for pot and atom economic synthesis of polycyclic spirooxindoles through α-C-H functionalization of cyclic amines has been developed. This highly efficient three-component [3+2] cycloaddition reaction was catalyzed by recyclable montmorillonite K10 and only water was produced as a byproduct.

KW - Heterogeneous catalysis

KW - Montmorillonite K10

KW - Recyclable

KW - Spirooxindoles

KW - [3+2] Cycloaddition

KW - α-C-H functionalization

UR - https://www.scopus.com/pages/publications/85044838225

UR - https://www.scopus.com/pages/publications/85044838225#tab=citedBy

U2 - 10.1021/acssuschemeng.8b00555

DO - 10.1021/acssuschemeng.8b00555

M3 - Article

AN - SCOPUS:85044838225

SN - 2168-0485

VL - 6

SP - 5574

EP - 5579

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

IS - 4

ER -

One-Pot Synthesis of Polycyclic Spirooxindoles via Montmorillonite K10-Catalyzed C-H Functionalization of Cyclic Amines

Abstract

ASJC Scopus Subject Areas

Keywords

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