Oxyanion Concentrations in Eastern Sierra Nevada Rivers - 2. Arsenic and Phosphate

Water samples were collected from the Truckee River-Pyramid Lake system, the Walker River-Walker Lake system, and the Carson River, all located in eastern California and western Nevada, U.S.A., at three different times (i.e., summer 1991, spring 1992, and autumn 1992) over a two year period. The concentrations of As, Na, Cl, ΣPO₄, and pH were measured in these river samples and the associated terminal lakes. Arsenic values ranged from below 13 nmol/kg near Truckee, California to 160 nmol/kg at Nixon, Nevada in the Truckee River, from 40 nmol/kg in the headwaters of both West and East Walker Rivers to 270 nmol/kg below Weber Reservoir on the main branch of the Walker River, and from <27 nmol/kg to 234 nmol/kg for the lower Carson River system. Arsenic concentrations in Steamboat Creek (0.91 μmol/kg-1.80 μmol/kg) in the Truckee River catchment are above the U.S. EPA drinking water maximum contaminant level of 0.67 μmol/kg, as are the As concentrations in both Pyramid Lake (1.33 μmol/kg-1.57 μmol/kg ) and Walker Lake (13.7 μmol/kg-18.7 μmol/kg). Sources of As for all three rivers include weathering of As-rich rocks and/or regolith and input of high-As geothermal spring waters, both processes primarily, although not exclusively, adding As to the headwater regions of these rivers. Steamboat Hot Springs (29 μmol/kg ≤ As ≤ 54.5 μmol/kg), for example, is identified as a source of As to the Truckee River via Steamboat Creek. The high As concentrations in Pyramid and Walker Lakes are likely due to (1) desorption of arsenate from aquatic particulate matter in these high pH waters (9.0 ≤ pH ≤ 9.5), (2) limited biologic uptake of arsenate, and (3) evaporative concentration of the lake waters. Evaluation of molar ΣPO₄/As ratios of river waters and geothermal spring waters (e.g., Steamboat Hot Springs), indicates that phosphate is substantially enriched in Steamboat Creek as well as the mid to lower reaches of the Walker and Carson Rivers. These regions of each river are dominated by agricultural interests and, additionally, in the case of Steamboat Creek, residential areas and golf courses. Our data strongly imply that phosphate-rich agricultural return flow has likely added P to these streams and, consequently, increased their respective P:As ratios.