Phosphinoyl Radical-Initiated 1,2-Bifunctional Thiocyanodiphenylphosphinoylation of Alkenes

Ze Kun Tao; Cheng Kun Li; Pei Zhi Zhang; Adedamola Shoberu; Jian Ping Zou; Wei Zhang

doi:10.1021/acs.joc.7b02929

Phosphinoyl Radical-Initiated 1,2-Bifunctional Thiocyanodiphenylphosphinoylation of Alkenes

Ze Kun Tao
, Cheng Kun Li
, Pei Zhi Zhang
, Adedamola Shoberu
, Jian Ping Zou
, Wei Zhang

Chemistry

Soochow University

Research output: Contribution to journal › Article › peer-review

Abstract

1,2-Bifuctional thiocyanodiphenylphosphinoylation of alkenes is established through the phosphinoyl radical addition followed by Cu-catalyzed thiocyanation. This one-pot reaction is applicable to a range of aromatic, aliphatic, and cyclic alkenes to afford thiocyanodiphenylphosphinoylated compounds in satisfactory yields.

Original language	English
Pages (from-to)	2418-2424
Number of pages	7
Journal	Journal of Organic Chemistry
Volume	83
Issue number	4
DOIs	https://doi.org/10.1021/acs.joc.7b02929
State	Published - Feb 16 2018

ASJC Scopus Subject Areas

Organic Chemistry

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title = "Phosphinoyl Radical-Initiated 1,2-Bifunctional Thiocyanodiphenylphosphinoylation of Alkenes",

abstract = "1,2-Bifuctional thiocyanodiphenylphosphinoylation of alkenes is established through the phosphinoyl radical addition followed by Cu-catalyzed thiocyanation. This one-pot reaction is applicable to a range of aromatic, aliphatic, and cyclic alkenes to afford thiocyanodiphenylphosphinoylated compounds in satisfactory yields.",

author = "Tao, \{Ze Kun\} and Li, \{Cheng Kun\} and Zhang, \{Pei Zhi\} and Adedamola Shoberu and Zou, \{Jian Ping\} and Wei Zhang",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

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doi = "10.1021/acs.joc.7b02929",

language = "English",

volume = "83",

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journal = "Journal of Organic Chemistry",

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T1 - Phosphinoyl Radical-Initiated 1,2-Bifunctional Thiocyanodiphenylphosphinoylation of Alkenes

AU - Tao, Ze Kun

AU - Li, Cheng Kun

AU - Zhang, Pei Zhi

AU - Shoberu, Adedamola

AU - Zou, Jian Ping

AU - Zhang, Wei

PY - 2018/2/16

Y1 - 2018/2/16

N2 - 1,2-Bifuctional thiocyanodiphenylphosphinoylation of alkenes is established through the phosphinoyl radical addition followed by Cu-catalyzed thiocyanation. This one-pot reaction is applicable to a range of aromatic, aliphatic, and cyclic alkenes to afford thiocyanodiphenylphosphinoylated compounds in satisfactory yields.

AB - 1,2-Bifuctional thiocyanodiphenylphosphinoylation of alkenes is established through the phosphinoyl radical addition followed by Cu-catalyzed thiocyanation. This one-pot reaction is applicable to a range of aromatic, aliphatic, and cyclic alkenes to afford thiocyanodiphenylphosphinoylated compounds in satisfactory yields.

UR - https://www.scopus.com/pages/publications/85042183485

UR - https://www.scopus.com/pages/publications/85042183485#tab=citedBy

U2 - 10.1021/acs.joc.7b02929

DO - 10.1021/acs.joc.7b02929

M3 - Article

C2 - 29376357

AN - SCOPUS:85042183485

SN - 0022-3263

VL - 83

SP - 2418

EP - 2424

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 4

ER -

Phosphinoyl Radical-Initiated 1,2-Bifunctional Thiocyanodiphenylphosphinoylation of Alkenes

Abstract

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