Abstract
We present numerical results for rate coefficients of reaction and vibrational quenching in the collision of H with D2 (v, j) at cold and ultracold temperatures. We explore both ortho-D2( j=0) and para-D2 ( j=1) for several initial vibrational states (v ≤5), and find resonant structures in the energy range 0.0110 K, which are sensitive to the initial rovibrational state (v, j). We compare the reaction rates for D2 + H with our previously obtained results for the isotopologue reaction H2 + D, and discuss the implications of our detailed study of this benchmark system for ultracold chemistry.
| Original language | English |
|---|---|
| Article number | 104001 |
| Journal | Journal of Physics B: Atomic, Molecular and Optical Physics |
| Volume | 50 |
| Issue number | 10 |
| DOIs | |
| State | Published - Apr 21 2017 |
ASJC Scopus Subject Areas
- Atomic and Molecular Physics, and Optics
- Condensed Matter Physics
Keywords
- deuterium
- molecular hydrogen
- resonances
- ultracold chemistry
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